Stereomutation at an Octahedral Transition-Metal Center: Energetics of Hydride Transit between Syn and Anti Faces of the Bis(diphenylphosphinopropyl)(methyl)silyl (biPSi) Complex RuH(biPSi)(CO)2-Reference-Cited by-同舟云学术

Stereomutation at an Octahedral Transition-Metal Center: Energetics of Hydride Transit between Syn and Anti Faces of the Bis(diphenylphosphinopropyl)(methyl)silyl (biPSi) Complex RuH(biPSi)(CO)2

Published:2001-04-19 Issue:10 Volume:20 Page:1898-1900
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Zhou Xiaobing (“Joe”)¹,Stobart Stephen R.¹

Affiliation:

1. Department of Chemistry, University of Victoria, British Columbia, Canada V8W 2Y2

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0100939

Reference19 articles.

1. Stereodirection of nucleophilic addition to five-coordinated complexes of iridium

2. Associative Stereomutation of a Pentacoordinate Transition-Metal Complex: Access to the Required Octahedral Intermediate through Stereoselective CO Uptake at an Unsaturated Ruthenium(II) Center

3. Theoretical study of the structures of electron-deficient d6 ML5 complexes. Importance of a .pi.-donating ligand

4. Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of Pt[SiMe(CH2CH2CH2PPh2)2]Cl, IrH[SiMe(CH2CH2CH2PPh2)2]Cl, and RuH[SiMe(CH2CH2CH2PPh2)2](CO)21

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