Associative Stereomutation of a Pentacoordinate Transition-Metal Complex: Access to the Required Octahedral Intermediate through Stereoselective CO Uptake at an Unsaturated Ruthenium(II) Center-Reference-Cited by-同舟云学术

Associative Stereomutation of a Pentacoordinate Transition-Metal Complex: Access to the Required Octahedral Intermediate through Stereoselective CO Uptake at an Unsaturated Ruthenium(II) Center

Published:2001-01-26 Issue:4 Volume:20 Page:601-603
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Bushnell Gordon W.¹,Casado Miguel Angel¹,Stobart Stephen R.¹

Affiliation:

1. Department of Chemistry, University of Victoria, British Columbia, Canada V8W 2Y2

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0009482

Reference15 articles.

1. The Mechanistic Basis for Electronic Effects on Enantioselectivity in the (salen)Mn(III)-Catalyzed Epoxidation Reaction

2. Electronically Dissymmetric DIPHOS Derivatives Give Higher n:i Regioselectivity in Rhodium-Catalyzed Hydroformylation Than Either of Their Symmetric Counterparts

3. Phosphinoalkylsilyl Complexes. 12. Stereochemistry of the Tridentate Bis(diphenylphosphinopropyl)silyl (biPSi) Framework: Complexation That Introduces “Face Discrimination” at Coordinatively Unsaturated Metal Centers. X-ray Crystal and Molecular Structures of Pt[SiMe(CH2CH2CH2PPh2)2]Cl, IrH[SiMe(CH2CH2CH2PPh2)2]Cl, and RuH[SiMe(CH2CH2CH2PPh2)2](CO)21

4. (Phosphinoalkyl)silanes. 2. Synthesis and spectroscopic properties of the poly(phosphinoalkyl)silanes SiHR[(CH2)nPR'2]2 (R = Me or Ph; n = 2 or 3; R' = Ph or cyclohexyl) and SiH[(CH2)nPR'2]3 (R = Me or Ph; n = 2, R' = Ph or cyclohexyl; n = 3, R' = Ph)

5. Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes

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