Challenges in Predicting ΔrxnG in Solution: The Mechanism of Ether-Catalyzed Hydroboration of Alkenes
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Regina, 3737 Wascana Parkway, Regina, SK S4S 0A2, Canada
2. Department of Industrial Systems Engineering, University of Regina, 3737 Wascana Parkway, Regina, SK S4S 0A2, Canada
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Foundation for Innovation
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp507793v
Reference46 articles.
1. Boron Reagents in Process Chemistry: Excellent Tools for Selective Reductions
2. Hydroboration Kinetics. 6.1 Hydroboration of Alkenes with 9-Borabicyclo[3.3.1]nonane Dimer and 9-Borabicyclo[3.3.1]nonane-Lewis Base Complexes in Various Solvents: An Interpretation of the Catalytic Effect of Ether Solvents on the Hydroboration Reaction
3. Transfer reactions involving boron. XXIV. Measurement of the kinetics and activation parameters for the hydroboration of tetramethylethylene and measurement of isotope effects in the hydroboration of alkenes
4. Transfer reactions involving boron. XXV. Measurement of the relative rate ratios of the first and second steps of the hydroboration reaction and the rates of alkylborane redistribution reactions. Discussion of the overall mechanism of the hydroboration reaction
5. Mechanism of hydroboration of alkenes with borane-Lewis base complexes. Evidence that the mechanism of the hydroboration reaction proceeds through a prior dissociation of such complexes
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