An experimental, computational, and uncertainty analysis study of the rates of iodoalkane trapping by DABCO in solution phase organic media-Reference-Cited by-同舟云学术

An experimental, computational, and uncertainty analysis study of the rates of iodoalkane trapping by DABCO in solution phase organic media

Published:2023 Issue:9 Volume:25 Page:6914-6926
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Grubel Katarzyna¹^ORCID,Rosenthal W. Steven¹^ORCID,Autrey Tom¹^ORCID,Henson Neil J.¹²^ORCID,Koh Katherine¹^ORCID,Flowers Sarah¹³,Blake Thomas A.¹^ORCID

Affiliation:

1. Pacific Northwest National Laboratory, P.O. Box 999, Mail Stop K4-13, Richland, WA 99352, USA

2. Department of Chemistry, Washington State University, Pullman, WA 99164, USA

3. Boston Heart Diagnostics, 31 Gage St., Needham, MA 02492, USA

Abstract

The calculated transition state structure of 1-iodobutane reacting with DABCO is shown. The kinetic rates of this reaction in several organic solvents and temperatures have been measured along with those of iodomethane reacting with DABCO.

Funder

U.S. Department of Energy

Laboratory Directed Research and Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05286E

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