Asymmetric Deprotonation of N-Boc Piperidine: React IR Monitoring and Mechanistic Aspects-Reference-Cited by-同舟云学术

Asymmetric Deprotonation of N-Boc Piperidine: React IR Monitoring and Mechanistic Aspects

Published:2010-05-12 Issue:21 Volume:132 Page:7260-7261
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Stead Darren¹,Carbone Giorgio¹,O’Brien Peter¹,Campos Kevin R.¹,Coldham Iain¹,Sanderson Adam¹

Affiliation:

1. Department of Chemistry, University of York, Heslington, York YO10 5DD, U.K., Department of Process Research, Merck Research Laboratories, Rahway, New Jersey 07065, Department of Chemistry, University of Sheffield, Brook Hill, Sheffield, S3 7HF, U.K., and Eli Lilly and Co. Ltd., Lilly Research Centre, Erl Wood Manor, Sunninghill Road, Windlesham, Surrey, GU20 6PH, U.K.

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja102043e

Reference22 articles.

1. Complex Induced Proximity Effects: Enantioselective Syntheses Based on Asymmetric Deprotonations of N-Boc-pyrrolidines

2. An Experimental and Computational Investigation of the Enantioselective Deprotonation of Boc-piperidine

3. For other examples of low yielding lithiations of 6-ringN-Boc heterocycles using RLi/(−)-sparteine, see:

4. Diastereoselective synthesis of sparteine analogues via lithiation–electrophilic quench of N-Boc bispidines

5. An Experimental and Theoretical Study of the Asymmetric Lithiation of 1,2,3,5,6,7-Hexahydro-3a,4a-diazacyclopenta[def]phenanthren-4-one

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