Horizontal and Vertical Push Effects in Saddled Zinc Porphyrin Complexes: Implications for Heme Distortion
Author:
Affiliation:
1. Key Laboratory of Theoretical Organic Chemistry and Functional Molecules, Ministry of Education, and School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
Funder
China Scholarship Council
National Natural Science Foundation of China
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b03219
Reference74 articles.
1. Structure and Chemistry of Cytochrome P450
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3. The Conserved Trp–Cys Hydrogen Bond Dampens the “Push Effect” of the Heme Cysteinate Proximal Ligand during the First Catalytic Cycle of Nitric Oxide Synthase
4. The stereochemistry of peroxidase catalysis.
5. The Poulos−Kraut Mechanism of Compound I Formation in Horseradish Peroxidase: A QM/MM Study
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