Nonplanar porphyrins: synthesis, properties, and unique functionalities

Author:

Ishizuka Tomoya1ORCID,Grover Nitika2ORCID,Kingsbury Christopher J.2ORCID,Kotani Hiroaki1ORCID,Senge Mathias O.3ORCID,Kojima Takahiko1ORCID

Affiliation:

1. Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba and CREST (JST), 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan

2. School of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, Trinity College Dublin, The University of Dublin, 152-160 Pearse Street, Dublin 2, Ireland

3. Institute for Advanced Study (TUM-IAS), Technical University of Munich, Focus Group – Molecular and Interfacial Engineering of Organic Nanosystems, Lichtenbergstrasse 2a, 85748 Garching, Germany

Abstract

This review summarizes the chemistry of nonplanar porphyrins in terms of synthetic strategy, structural features governing their properties, unique functionalities derived from ring distortion, and further development of related research.

Funder

Iketani Science and Technology Foundation

Yazaki Memorial Foundation for Science and Technology

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Institute for Advanced Study, Technische Universität München

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference539 articles.

1. D.Dolphin , The Porphyrins , Academic Press , New York , 1978

2. K. M.Kadish , K. M.Smith and R.Guilard , The Porphyrin Handbook , Academic Press , New York , 2000 , vol. 2003

3. K. M.Kadish , K. M.Smith and R.Guilard , Handbook of Porphyrin Science , World Scientific , Singapore , 2010

4. Exercises in molecular gymnastics—bending, stretching and twisting porphyrins

5. The Photosynthetic Reaction Center from the Purple BacteriumRhodopseudomonas viridis(Nobel Lecture)

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