Modulation of iron spin states in highly distorted iron(iii) porphyrins: H-bonding interactions and implications in hemoproteins

Author:

Sahoo Dipankar1,Mazumdar Rakesh1,Pramanik Subhadip1,Banerjee Sayantani1,Patra Ranjan12ORCID,Rath Sankar Prasad1ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India

2. Amity Institute of Click Chemistry Research and Studies, Amity University, Noida, Uttar Pradesh, India

Abstract

A family of five- and six-coordinated Fe-porphyrins has been reported which enable us to scrutinize the effects of H-bonding interactions on the out-of-plane displacement of iron and its spin-state.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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