Comparative Experimental and Theoretical Study of the C and O K-Edge X-ray Absorption Spectroscopy in Three Highly Popular, Low Spin Organoiron Complexes: [Fe(CO)5], [(η5-C5H5)Fe(CO)(μ-CO)]2, and [(η5-C5H5)2Fe]-Reference-Cited by-同舟云学术

Comparative Experimental and Theoretical Study of the C and O K-Edge X-ray Absorption Spectroscopy in Three Highly Popular, Low Spin Organoiron Complexes: [Fe(CO)5], [(η5-C5H5)Fe(CO)(μ-CO)]2, and [(η5-C5H5)2Fe]

Published:2019-11-22 Issue:24 Volume:58 Page:16411-16423
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Carlotto Silvia¹^ORCID,Finetti Paola²,de Simone Monica³,Coreno Marcello⁴^ORCID,Casella Girolamo⁵^ORCID,Sambi Mauro¹⁶^ORCID,Casarin Maurizio¹⁷

Affiliation:

1. Dipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Francesco Marzolo 1, 35131 Padova, Italy

2. Dipartimento di Scienze e Metodi dell’Ingegneria, Università di Modena, Via Università 4, 41121 Modena, Italy

3. CNR−IOM, Strada Statale 14 Basovizza, 34149 Trieste, Italy

4. CNR−ISM, Strada Statale 14 Basovizza, 34149 Trieste, Italy

5. Dipartimento di Scienze della Terra e del Mare, Università degli Studi di Palermo, Via Archirafi 22, 90123 Palermo, Italy

6. Consorzio INSTM, Unità di Ricerca di Padova, Via Marzolo 1, 35131 Padova, Italy

7. CNR−ICMATE, Via Francesco Marzolo 1, 35131 Padova, Italy

Funder

Universit? degli Studi di Padova

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.9b02107

Reference82 articles.

1. aBianconi, A. X-ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS, and XANES, Koningsberger, D. C., Prins, R., Eds. John Wiley & Sons: New York, 1988; pp 573–662.

2. NEXAFS Spectroscopy

3. L-edge X-ray Absorption Spectroscopy of Non-Heme Iron Sites: Experimental Determination of Differential Orbital Covalency

4. Fe L-Edge XAS Studies of K4[Fe(CN)6] and K3[Fe(CN)6]: A Direct Probe of Back-Bonding

5. Fe L-Edge X-ray Absorption Spectroscopy of Low-Spin Heme Relative to Non-heme Fe Complexes: Delocalization of Fe d-Electrons into the Porphyrin Ligand

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