Electronic structures and properties of dianionic pentacarbonyls [TM(CO)5]2− (TM = Cr, Mo, W)-Reference-Cited by-同舟云学术

Electronic structures and properties of dianionic pentacarbonyls [TM(CO)5]2− (TM = Cr, Mo, W)

Published:2021 Issue:34 Volume:23 Page:18640-18646
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Pei Gerui¹,Shu Cong-Cong²,Li Mengyang¹,Sun Zhong-Ming²^ORCID,Yang Tao¹^ORCID

Affiliation:

1. Ministry of Education Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics, School of Physics, Xi’an Jiaotong University, Xi’an 710049, Shaanxi, China

2. State Key Laboratory of Element-Organic Chemistry, Tianjin Key Lab for Rare Earth Materials and Applications, School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

Stabilities, electronic structures, and vibrational and bonding properties of [TM(CO)5]2− (TM = Cr, Mo, W) have been studied and the π backdonations rather than σ donations were found to play a dominant role in stabilizing these dianions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01592C

Reference54 articles.

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