Large Effects of Ion Pairing and Protonic−Hydridic Bonding on the Stereochemistry and Basicity of Crown-, Azacrown-, and Cryptand-222-potassium Salts of Anionic Tetrahydride Complexes of Iridium(III)
Author:
Affiliation:
1. Davenport Laboratory, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6 Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic0255149
Reference35 articles.
1. Switching On and Off a New Intramolecular Hydrogen-Hydrogen Interaction and the Heterolytic Splitting of Dihydrogen. Crystal and Molecular Structure of [Ir{H(.eta.1-SC5H4NH)}2(PCy3)2]BF4.cntdot.2.7CH2Cl2
2. Organizing Chain Structures by Use of Proton−Hydride Bonding. The Single-Crystal X-ray Diffraction Structures of [K(Q)][Os(H)5(PiPr3)2] and [K(Q)][Ir(H)4(PiPr3)2], Q = 18-Crown-6 and 1,10-Diaza-18-crown-6
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