Estimating the Wavenumber of Terminal Metal-Hydride Stretching Vibrations of Octahedral d6 Transition Metal Complexes
Author:
Affiliation:
1. Department of Chemistry, University of Toronto, 80 Saint George St., Toronto, Ontario M5S3H6, Canada
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b02314
Reference251 articles.
1. Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes
2. Dihydrogen vs. dihydride. Correlations between electrochemical or UV PES data and force constants for carbonyl or dinitrogen ligands in octahedral, d6 complexes and their use in explaining the behavior of the dihydrogen ligand
3. Ligand additivity effects and periodic trends in the stability and acidity of octahedral .eta.2-dihydrogen complexes of d6 transition metal ions
4. Density Functional Theory Calculations Support the Additive Nature of Ligand Contributions to the pKa of Iron Hydride Phosphine Carbonyl Complexes
5. DFT methods applied to answer the question: how accurate is the ligand acidity constant method for estimating the pKa of transition metal hydride complexes MHXL4 when X is varied?
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