The Trifluoromethyl Anion: Evidence for [K(crypt-222)]+ CF3−-Reference-Cited by-同舟云学术

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The Trifluoromethyl Anion: Evidence for [K(crypt-222)]+ CF3−

Published:2017-04 Issue:4 Volume:100 Page:e1700032
ISSN:0018-019X
Container-title:Helvetica Chimica Acta
language:en
Short-container-title:Helv. Chim. Acta

Author:

Miloserdov Fedor M.¹,Konovalov Andrey I.¹,Martin Eddy¹,Benet-Buchholz Jordi¹,Escudero-Adán Eduardo C.¹,Lishchynskyi Anton¹,Grushin Vladimir V.¹

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ); Barcelona Institute of Science and Technology; ES-Tarragona

Funder

Institut Català d'Investigació Química

Publisher

Wiley

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Drug Discovery,Biochemistry,Catalysis

Link

http://onlinelibrary.wiley.com/wol1/doi/10.1002/hlca.201700032/fullpdf

Reference43 articles.

1. Fluorocarbanions. Rates of Base-Catalyzed Hydrogen-Deuterium Exchange, Isotope Effects, and Acidity of Monohydrofluorocarbons;Andreades;J. Am. Chem. Soc.,1964

2. Electroorganic Chemistry. 130. A Novel Trifluoromethylation of Aldehydes and Ketones Promoted by an Electrogenerated Base;Shono;J. Org. Chem.,1991

3. A. Kruse G. Siegemund A. Schumann I. Ruppert 1989 1 7

4. A. Kruse G. Siegemund A. Schumann 1990 1 5

5. Fluoride-Induced Trifluoromethylation of Carbonyl Compounds with Trifluoromethyltrimethylsilane (TMS-CF3). A Trifluoromethide Equivalent;Prakash;J. Am. Chem. Soc.,1989

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1. TMSCF₃-Mediated Conversion of Salicylates into α,α-Difluoro-3-coumaranones: Chain Kinetics, Anion-Speciation, and Mechanism;The Journal of Organic Chemistry;2023-12-02

2. Ex-situ generation and synthetic utilization of bare trifluoromethyl anion in flow via rapid biphasic mixing;Nature Communications;2023-03-03

3. In Situ Studies of Arylboronic Acids/Esters and R₃SiCF₃ Reagents: Kinetics, Speciation, and Dysfunction at the Carbanion–Ate Interface;Accounts of Chemical Research;2022-04-18

4. Mechanism of Anion-Catalyzed C–H Silylation Using TMSCF3: Kinetically-Controlled CF3-Anionoid Partitioning As a Key Parameter;ACS Catalysis;2021-02-22

5. Synthesis of trifluoromethyl ketones by nucleophilic trifluoromethylation of esters under a fluoroform/KHMDS/triglyme system;Beilstein Journal of Organic Chemistry;2021-02-12

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