Relationship between Basicity, Strain, and Intramolecular Hydrogen-Bond Energy in Proton Sponges
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Cardiff, Cardiff CF10 3TB, UK
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0010094
Reference33 articles.
1. Electron correlation effect on the geometries and energetics: Proton‐bound ammonia dimer, (H3N–H‐‐NH3)+
2. Y-Conjugated compounds: the equilibrium geometries and electronic structures of guanidine, guanidinium cation, urea, and 1,1-diaminoethylene
3. Harnessing steric strain to obtain superbases
4. Conformers, Energetics, and Basicity of 2,2‘-Bipyridine
5. Ab Initio Quantum Mechanical Study on the Origin of the pKa Differences of the Proton Sponges 1,8-Bis(dimethylamino)naphthalene, 1,8-Bis(dimethylamino)-2,7-dimethoxynaphthalene, 1,6-Dimethyl-1,6-diazacyclodecane, and 1,6-Diazabicyclo[4.4.4]tetradecane
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