Stereoselective ring-opening polymerization of <i>rac</i>-lactide catalyzed by the proton sponge bisphosphazene 1,8-bis(hexamethyltriaminophosphazenyl)naphthalene-Reference-Cited by-同舟云学术

Stereoselective ring-opening polymerization of rac-lactide catalyzed by the proton sponge bisphosphazene 1,8-bis(hexamethyltriaminophosphazenyl)naphthalene

Published:2024 Issue:21 Volume:15 Page:2212-2219
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Zhang Zhenqing¹,Guo Xiaoyu¹,Kou Xinhui²^ORCID,Zhao Na¹,Li Zhibo¹³^ORCID

Affiliation:

1. Key Laboratory of Biobased Polymer Materials, Shandong Provincial Education Department, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

2. Analyses and Testing Center, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

3. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

Abstract

Stereoselective ring-opening polymerization of rac-lactide was catalyzed by the proton sponge bisphosphazene HMPN, affording semicrystalline isotactic polylactide with Pm up to 0.93.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00242C

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