Ab Initio Quantum Mechanical Study on the Origin of the pKa Differences of the Proton Sponges 1,8-Bis(dimethylamino)naphthalene, 1,8-Bis(dimethylamino)-2,7-dimethoxynaphthalene, 1,6-Dimethyl-1,6-diazacyclodecane, and 1,6-Diazabicyclo[4.4.4]tetradecane
Author:
Affiliation:
1. University of Joensuu, Department of Chemistry, FIN-80101, Joensuu, Finland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo9606618
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1. ?Proton Sponges? and the Geometry of Hydrogen Bonds: Aromatic Nitrogen Bases with Exceptional Basicities
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4. X-ray, FTIR,1H and13C NMR, PM3 and AM1 studies of (N—H⋯N)+and (O—H⋯O)–hydrogen bonds in a complex of 1,8-diaminonaphthalene with maleic acid: proton cavity and basicity of proton sponges
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