The design of <i>C</i><sub>2</sub>-chiral bases with dual basic sites predicted to exceed the range of superbasicity: a computational study-Reference-Cited by-同舟云学术

The design of C₂-chiral bases with dual basic sites predicted to exceed the range of superbasicity: a computational study

Published:2022 Issue:40 Volume:46 Page:19381-19390
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Saha Anusuya¹²,Ganguly Bishwajit¹²^ORCID

Affiliation:

1. Computation and Simulation Unit, Analytical and Environmental Science Division and Centralized Instrument Facility, CSIR-Central Salt & Marine Chemicals Research Institute, Bhavnagar, Gujarat-364002, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India

Abstract

A set of C2-chiral bases with bis-protonation sites (1–9) on dimethyl-binaphthalene derivatives have been explored using the B3LYP/6-311+G(d,p) level and the proton affinities calculated are in the range of superbases for both the sites.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03537E

Reference37 articles.

1. Activating Pronucleophiles with High p K a Values: Chiral Organo‐Superbases

2. Higher-Order Cyclopropenimine Superbases: Direct Neutral Brønsted Base Catalyzed Michael Reactions with α-Aryl Esters

3. Development of Chiral Ureates as Chiral Strong Brønsted Base Catalysts

4. Asymmetric organocatalysis by chiral Brønsted bases: implications and applications

5. Design of C2-Chiral Diamines That Are Computationally Predicted To Be a Million-fold More Basic than the Original Proton Sponges

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Biguanide-dihydropyrimidine dual scaffolds with impressive basicities according to DFT calculations;Computational and Theoretical Chemistry;2023-07