Reductive Openings of Benzylidene Acetals Revisited: A Mechanistic Scheme for Regio- and Stereoselectivity
Author:
Affiliation:
1. Organic Chemistry, Lund University, P.O. Box 124, SE-221 00 Lund, Sweden
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo101184d
Reference40 articles.
1. CLEAVAGE OF SAPOGENIN TERMINAL RINGS WITH LITHIUM ALUMINUM HYDRIDE
2. THE INFLUENCE OF SUBSTITUENTS ON THE EASE AND DIRECTION OF RING OPENING IN THE LiAlH4–AlCl3 REDUCTIVE CLEAVAGE OF SUBSTITUTED 1,3-DIOXOLANES
3. THE RELATIVE EASE OF REDUCTIVE CLEAVAGE OF 1,3-DIOXOLANES AND 1,3-DIOXANES IN ETHER SOLUTION BY LiAlH4–AlCl3
4. Stereoselective ring-cleavage of 3-O-benzyl- and 2,3-di-O-benzyl-4,6-O-benzylidenehexopyranoside derivatives with the LiAlH4AlCl3, reagent
5. Chemo-, stereo- and regioselective hydrogenolysis of carbohydrate benzylidene acetals. Synthesis of benzyl ethers of benzyl α-d-, methyl β-D-mannopyranosides and benzyl α-D-rhamnopyranoside by ring cleavage of benzylidene derivatives with the LiAlH4-AlCl3 reagent
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