Author:
Leggetter B. E.,Diner U. E.,Brown R. K.
Abstract
In ether solution, 1,3-dioxolanes are hydrogenolyzed faster by LiAlH4–AlCl3 than are the corresponding 1,3-dioxanes. This difference is attributed to the relative ease of oxocarbonium ion formation in the rate-determining step of the reaction. The results obtained have been utilized to explain the selective cleavage of the five- and six-membered acetal structures found in the polyacetals of hexitols.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
20 articles.
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