Reversible Isomerization of a Diphosphine Ligand about a Triosmium Cluster: Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3(CO)10[(Z)-Ph2PCHCHPPh2]-Reference-Cited by-同舟云学术

Reversible Isomerization of a Diphosphine Ligand about a Triosmium Cluster: Synthesis, Kinetics, and X-ray Structures for the Bridging and Chelating Isomers of Os3(CO)10[(Z)-Ph2PCHCHPPh2]

Published:2005-09-29 Issue:22 Volume:24 Page:5431-5439
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Watson William H.¹,Wu Guanmin²,Richmond Michael G.²

Affiliation:

1. Department of Chemistry, Texas Christian University, Fort Worth, Texas 76129

2. Department of Chemistry, University of North Texas, Denton, Texas 76203

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0505413

Reference71 articles.

1. Bridging versus chelating diphosphine in clusters: Isomers of Os3(CO)10(diphosphine)

2. Protonation and hydrogenation of triosmium clusters containing the bridging diphosphine ligands Ph2P(CH2nPPh2 (n  1 to 4)

3. Synthesis, single-crystal X-ray structures, and fluxional behaviour of 1,2-[Os3(CO)10(µ-dppe)] and its protonated derivative 1,2-[Os3(µ-H)(CO)10(µ-dppe)][PF6] where dppe = Ph2PCH2CH2PPh2

4. Trinuclear clusters of osmium containing monodentate, chelating and orthometallated forms of 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (BINAP)

5. Reactions of metal carbonyl cluster complexes with multidentate phosphine ligands; preparation of bis(diphenylphosphino)methane derivatives of the trinuclear complexes M3(CO)12 (M = Fe, Ru and Os) and the X-ray crystal structure of Os3(CO)9(μ-dppm)(η1-dppm) (dppm = Ph2pch2ppH2)

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1. Kinetic and computational investigation on the reaction of Os5C(CO)15 with (Z)-Ph2PCH=CHPPh2 (dppen): Stepwise conversion to nido Os5C(CO)13(κ2-Pa,Pb-dppen);Journal of Organometallic Chemistry;2023-11

2. Bimodal substitution behavior in the reaction of N,N’-diisopropylformamidine with [Os3(CO)10(NCMe)2]: Kinetics and molecular structures of the formamidinate-substituted clusters HOs3(CO)9[μ-C(O)NPr C(H)NPr ], HOs3(CO)10[μ-NPr C(H)NPr ], and HOs3(CO)9[μ3-NPr C(H)NPr ];Journal of Organometallic Chemistry;2021-03

3. Chiral diphosphine derivatives of alkylidyne tricobalt carbonyl clusters – A comparative study of different cobalt carbonyl (pre)catalysts for (asymmetric) intermolecular Pauson–Khand reactions;Polyhedron;2016-01

4. Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(trans-dpmn) and 1,2-Os3(CO)10(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os3(CO)10(dpmn) and Isomer-Dependent Diphosphine Ligand Activation;Journal of Cluster Science;2014-07-23

5. Backbone modified small bite-angle diphosphines: Synthesis, structure, and DFT evaluation of the thermal activation products based on Os3(CO)10{μ-Ph2PC(Me)2PPh2};Journal of Organometallic Chemistry;2014-01