Protonation and hydrogenation of triosmium clusters containing the bridging diphosphine ligands Ph2P(CH2nPPh2 (n 1 to 4)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference29 articles.
1. Triosmium Clusters
2. Isolation of intermediates in metal carbonyl substitution: Adducts of H2Os3(CO)10
3. Addition reactions of a polynuclear osmium hydrido compound leading to associative carbonyl substitution and catalytic alkene isomerisation
4. Synthesis and characterization of the fluxional species H2Os3(CO)10L. Crystal structure of dihydroundecacarbonyltriosmium
5. Solution structures and dynamics of complexes of decacarbonyldihydrotriosmium with Lewis bases
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1. Reactivity of unsaturated [HOs3(CO)8{µ3-Ph2PCH2PPh(C6H4)}] towards activated alkynes RC CR (R=CO2Et, CO2Me);Inorganica Chimica Acta;2021-01
2. Thermolysis of [HOs3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}]: New Os2- and Os3- cluster products based on multiple C H bond activation of the bis(diphenylphosphino)methane ligand;Inorganica Chimica Acta;2020-09
3. An exhibition of different coordination modes displayed by 2-vinylpyrazine and 2-vinylpyridine at triosmium centres;Journal of Organometallic Chemistry;2017-11
4. Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes;Journal of Organometallic Chemistry;2017-05
5. Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes;Chemical Reviews;2016-03-10
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