Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes-Reference-Cited by-同舟云学术

Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes

Published:2017-05 Issue: Volume:836-837 Page:68-80
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Chowdhury Md. Arshad H.,Haque Mohd. Rezaul,Ghosh Shishir,Mobin Shaikh M.,Tocher Derek A.,Hogarth Graeme,Richmond Michael G.,Kabir Shariff E.^ORCID,Roesky Herbert W.

Funder

Robert A. Welch Foundation

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference115 articles.

1. The high yield synthesis of an unsaturated osmium cluster; the X-ray crystal structure of [Os3(CO)8(H){Ph2PCH2P(Ph)C6H4}]

2. The preparation of an unsaturated hydrido osmium cluster by hydrogenolysis of a cyclometallated phosphine; the X-ray structure of [Os3(CO)8(H)2(Ph2PCH2PPh2)]

3. Electronic control of the co-ordination mode of an alkyne to a trimetallic cluster; X-ray crystal structure of Os3(CO)7(µ3-η2(⊥)-PhCCPh)(Ph2PCH2PPh2)

4. Reactions of the co-ordinatively unsaturated cluster [Os3(µ-H)(CO)8{Ph2PCH2P(Ph)C6H4}] with alkynes RCCR (R = Ph, C6H4Me, Me or CF3); crystal structures of [Os3(CO)8{µ3–η2(∥)–RC2R}(Ph2PCH2PPh2)](R = Me or CF3) and electrochemical behaviour of triosmium–alkyne clusters

5. Reaction of the unsaturated triosmium clusters [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}] and [Os3H(CO)8{Ph2PC(CH2)P(Ph)C6H4}] with phosphines and phosphites; crystal structures of [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}(PPri3)], [Os3(CO)8(Ph2PCH2PPh2){P(OMe)3}2], and [Os3(CO)8(Ph2PCH2PPh2)(PPh3)2]

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1. Stereochemical control of the diphosphine and alkyne ligands in triruthenium clusters: The effect of reversible CO loss/addition on the ligand distribution in [Ru3(µ3,η2-PhCCPh){µ-Ph2PCH(Me)PPh2}(CO)7,8];Journal of Organometallic Chemistry;2022-06

2. Reactions of a Gallane(pyridyl)iron Complex with Internal and Terminal Alkynyl Esters: C−O and C−C Bond Cleavage and Oxidative Addition of C−H Bond;ChemistrySelect;2022-02-17

3. Reactivity of unsaturated [HOs3(CO)8{µ3-Ph2PCH2PPh(C6H4)}] towards activated alkynes RC CR (R=CO2Et, CO2Me);Inorganica Chimica Acta;2021-01

4. Carboxylated Chalcone and Benzaldehyde Derivatives of Triosmium Carbonyl Clusters: Synthesis, Characterization and Biological Activity Towards MCF-7 Cells;Journal of Cluster Science;2019-09-27

5. Activation of thiosaccharin at a polynuclear osmium cluster;Journal of Organometallic Chemistry;2019-02