Kinetic and computational investigation on the reaction of Os5C(CO)15 with (Z)-Ph2PCH=CHPPh2 (dppen): Stepwise conversion to nido Os5C(CO)13(κ2-Pa,Pb-dppen)
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference52 articles.
1. Systematic Kinetics of High-Nuclearity Metal Carbonyl Clusters. Exceptional Behavior of Ru5C(CO)15 with P-Donor Nucleophiles
2. Kinetics of associative reactions of Fe5C(CO)15 with P-donor nucleophiles
3. Kinetic and thermodynamic studies of reversible adduct formation between Ru5C(CO)15 and acetonitrile
4. Synthesis of the carbido anion [Os5C(CO)15I]? and the X-ray crystal structures of Os5C(CO)15 and [(Ph3P)2N][Os5C(CO)15I]
5. Activation of a carbonyl group in the pentanuclear carbido clusters Os5C(CO)15 and I2Os5C(CO)15 by alcohols: X-ray analysis of HOs5C(CO)14(CO2Et) and IOs5C(CO)14(CO2Me)
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