Reactions of the Carbyne-Bridged Radical Complex [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+ with Bidentate Ligands Having E–H Bonds (E = O, S, N)
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om401192m
Reference60 articles.
1. Cyclopentadienyl and related complexes of the group 6 elements having metal–metal triple bonds: Synthesis, structure, bonding and reactivity
2. Binuclear Carbyne and Ketenyl Derivatives of the Alkyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-CH2R)(μ-PCy2)(CO)2] (R = H, Ph)
3. Dehydrogenative Formation and Reactivity of the Unsaturated Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(μ-CO)]: C−C and C−P Coupling Reactions
4. Reversible P–C Coupling Reactions at the Unsaturated Dimolybdenum Carbyne Complex [Mo2(η5-C5H5)2(CPh)(μ-PCy2)(μ-SPh)(CO)]+
5. Facile bond-forming and -breaking process at phosphorus, carbon, and oxygen centres in tungsten–cobalt complexes: X-ray crystal structures of [WCo(OH)(µ-CC6H4Me-4)(µ-PPh2)2(CO)2(η-C5H5)], [WCo(O){µ-C(C66H4Me-4)C(O)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)], and the novel alkyne complex [WCo(O){µ-C(C6H4Me-4)C(OMe)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)][BF4]
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1. C≡N and N≡O Bond Cleavages of Acetonitrile and Nitrosyl Ligands at a Dimolybdenum Center to Render Ethylidyne and Acetamidinate Ligands;Inorganic Chemistry;2024-02-02
2. Reactivity of Cyclopentadienyl Molybdenum Compounds towards Formic Acid: Structural Characterization of CpMo(PMe3)(CO)2H, CpMo(PMe3)2(CO)H, [CpMo(μ-O)(μ-O2CH)]2, and [Cp*Mo(μ-O)(μ-O2CH)]2;Inorganic Chemistry;2017-01-19
3. The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2014;Coordination Chemistry Reviews;2016-06
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