Facile bond-forming and -breaking process at phosphorus, carbon, and oxygen centres in tungsten–cobalt complexes: X-ray crystal structures of [WCo(OH)(µ-CC6H4Me-4)(µ-PPh2)2(CO)2(η-C5H5)], [WCo(O){µ-C(C66H4Me-4)C(O)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)], and the novel alkyne complex [WCo(O){µ-C(C6H4Me-4)C(OMe)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)][BF4]-Reference-Cited by-同舟云学术

Facile bond-forming and -breaking process at phosphorus, carbon, and oxygen centres in tungsten–cobalt complexes: X-ray crystal structures of [WCo(OH)(µ-CC6H4Me-4)(µ-PPh2)2(CO)2(η-C5H5)], [WCo(O){µ-C(C66H4Me-4)C(O)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)], and the novel alkyne complex [WCo(O){µ-C(C6H4Me-4)C(OMe)}(µ-PPh2)(CO)(PPh2H)(η-C5H5)][BF4]

Published:1990 Issue:2 Volume: Page:170-172
ISSN:0022-4936
Container-title:J. Chem. Soc., Chem. Commun.
language:en
Short-container-title:J. Chem. Soc., Chem. Commun.

Author:

El Amin El Amin E.,Jeffery John C.,Walters Tracy M.

Publisher

Royal Society of Chemistry (RSC)

Subject

Molecular Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/1990/C3/C39900000170

Reference5 articles.

1. Synthesis and reactions of phosphido-bridged μ3-alkylidyne clusters; X-ray crystal structures of the complexes [Co2W(μ-PEt2)3(CO)5(η-C5H5)], [Co2W{μ3-C(R)C(Et)C(Et)C(O)}(μ-CO)(CO)4(PPh2{C(Et)CHEt})(η-C5H5)], and [CoW{μ-C(R)C(Et)C(Et)C(OH)}(CO)4(η-C5H5)] (R = C6H4Me-4)

2. Synthesis and reactions of co-ordinatively unsaturated µ3-alkylidyne clusters; X-ray crystal structures of the phosphido-bridged complexes [Fe2W(µ3-CR)(µ-H)(µ-PPh2)(CO)6(η-C5H5)], [Fe2W(µ3-CR)(µ-H)(µ-PEt2)(CO)6(PEt2H)(η-C5H5)], and [Fe2W(µ3-CR){µ-C(O)C(Me)CHMe}(µ-PEt2)(CO)5(η-C5H5)](R = C6H4Me-4)

3. Facile carbon–carbon and carbon–phosphorus bond-forming and -breaking processes in metal chain clusters: X-ray crystal structures of [W3Rh2(µ-CO)2(µ-CMe){µ-C(Me)C(O)}(µ-PPh2)2(µ3-CMe)(CO)2(η-C5H5)3] and [W3Rh2(µ-CO)3(µ-CMe){µ-C(Me)PPh2}(µ-PPh2)(µ3-CMe)(CO)2(η-C5H5)3]

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