Dehydrogenative Formation and Reactivity of the Unsaturated Benzylidyne-Bridged Complex [Mo2Cp2(μ-CPh)(μ-PCy2)(μ-CO)]: C−C and C−P Coupling Reactions
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om901053x
Reference24 articles.
1. Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions
2. Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives
3. Activation of µ-alkylidene ligands through oxidation–deprotonation: a new synthesis of µ-methyne, and is hydrogenation to µ-methyl
4. The making and breaking of carbon-hydrogen bonds on a metal cluster framework. Analysis of the tautomerization and deprotonation of Fe3(CO)9CH4 leading to the interconversion of FeHFe and CHFe interactions
5. Synthesis, structure, and property of a triruthenium cluster having a μ-alkyl ligand: Transformation of a μ3(⊥)-alkyne ligand into a μ-alkyl ligand via a μ3-vinylidene complex
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