Migratory insertion of isocyanide into a ketenyl–tungsten bond as key step in cyclization reactions-Reference-Cited by-同舟云学术

Migratory insertion of isocyanide into a ketenyl–tungsten bond as key step in cyclization reactions

Published:2022 Issue:1 Volume:13 Page:123-132
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Timmermann Christopher¹,Thiem Paula¹,Wanitschke Dominik¹²,Hüttenschmidt Mareike¹,Romischke Johanna¹,Villinger Alexander¹^ORCID,Seidel Wolfram W.¹²^ORCID

Affiliation:

1. Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany

2. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Straße 29a, D-18059 Rostock, Germany

Abstract

The prototype ketenyl ligand is bound end-on despite a formal 16 valence electron count at the metal. This situation opens a reaction pathway for a multicomponent cyclization centred on the migration of the ketenyl ligand.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06149F

Reference68 articles.

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2. Alternative Metals for Homogeneous Catalyzed Hydroformylation Reactions

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4. The Chemistry of Isocyanides, their MultiComponent Reactions and their Libraries

5. Migratory Insertion of an Isocyanide into 1-Zirconacyclopent-3-ynes

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