Pyrazolyl-Bridged Iridium Dimers. 18.1 Influence of Metal−Metal Bonding on the Geometry of Diiridium(II) Adducts and Hydrido-diiridium Complexes Formed from the Diiridium(I) Prototype [Ir(μ-pz)(PPh3)(CO)]2 (pzH = Pyrazole) by Dihydrogen Addition or Protonation
Author:
Affiliation:
1. Department of Chemistry, University of Victoria, Victoria, British Columbia, Canada V8W 2Y2
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic010448g
Reference25 articles.
1. Pyrazolyl-Bridged Iridium Dimers. 17.1 Tetrakis(alkene)diiridium(I) Complexes: [Ir(η2-C2H4)2(μ-Cl)]2 as a Precursor to [Ir(η2-C2H4)2(μ-pz)]2. Stereochemically Nonrigid Behavior of the Analogue [Ir(η2-C2H4)(η2-C2F4)(μ-Cl)]2
2. Organogold chemistry. XVII. Synthesis and reactions of the gold(I)-dimethylphosphonium-bis-methylid dimer
3. Pyrazolyl-bridged iridium dimers. 2. Contrasting modes of two-center oxidative addition to a bimetallic system and reductive access to the starting complex: three key diiridium structures representing short nonbonding and long and short bonding metal-metal interactions
4. Pyrazolyl-Bridged Iridium Dimers. 16.1 The Atropisomeric (C2) System [Ir(CO)(PPh3)(μ-pz)]2. Synthesis of Homologous Diastereomeric Complexes That Undergo Slow Stereomutation by Ring Inversion of the Bridging Framework: Mechanistic Implications for Bimetallic Substrate Activation
5. Co-operativity effects between adjacent metal sites—kinetics of methyl iodide addition to pyrazolyl-bridged iridium dimers: argument for a concerted mechanism in the reversible two-fragment, two-centre oxidative addition to the cyclo-octa-1,5-diene di-iridium(I) complex [Ir(COD)(µ-pz)]2
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