Reversible Displacement of Polyagostic Interactions in 16e [Mn(CO)(R2PC2H4PR2)2]+ by H2, N2, and SO2. Binding and Activation of η2-H2 trans to CO Is Nearly Invariant to Changes in Charge and cis Ligands-Reference-Cited by-同舟云学术

Reversible Displacement of Polyagostic Interactions in 16e [Mn(CO)(R2PC2H4PR2)2]+ by H2, N2, and SO2. Binding and Activation of η2-H2 trans to CO Is Nearly Invariant to Changes in Charge and cis Ligands

Published:1999-02-27 Issue:6 Volume:38 Page:1069-1084
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

King Wayne A.¹,Scott Brian L.¹,Eckert Juergen¹,Kubas Gregory J.¹

Affiliation:

1. Los Alamos National Laboratory, CST-18, MS-J514, Los Alamos, New Mexico 87545

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic981263l

Reference85 articles.

1. Dihydrogen versus Dihydride: Relativistic Effects on the Relative Stabilities of Nonclassical and Classical Isomers of M(PH3)3H4 (M = Fe, Ru, Os)

2. Periodic Trends and Ligand Effects in Transition Metal Dihydrogen Complexes: A Quasi-relativistic Density Functional Study

3. Structure and Bonding of Transition Metal Dihydrogen Complexes[M(CO)5(H2)](M= Cr, Mo, W)

4. Structure and Bonding of the Transition-Metal Carbonyl Complexes M(CO)5L (M = Cr, Mo, W) and M(CO)3L (M = Ni, Pd, Pt; L = CO, SiO, CS, N2, NO+, CN-, NC-, HCCH, CCH2, CH2, CF2, H2)1

5. Ab initio studies of transition-metal compounds: the nature of the chemical bond to a transition metal

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