“Ligandless” Pentafluoroethylation of Unactivated (Hetero)aryl and Alkenyl Halides Enabled by the Controlled Self-Condensation of TMSCF3-Derived CuCF3-Reference-Cited by-同舟云学术

“Ligandless” Pentafluoroethylation of Unactivated (Hetero)aryl and Alkenyl Halides Enabled by the Controlled Self-Condensation of TMSCF3-Derived CuCF3

Published:2019-10-03 Issue:23 Volume:84 Page:15087-15097
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Mestre Jordi¹^ORCID,Castillón Sergio¹,Boutureira Omar¹^ORCID

Affiliation:

1. Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/ Marcel·lí Domingo 1, 43007 Tarragona, Spain

Funder

Ministerio de Ciencia, Innovaci?n y Universidades

European Regional Development Fund

Universitat Rovira i Virgili

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.9b02001

Reference93 articles.

1. Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

2. Fluorination methods in drug discovery

3. Fluorination methods for drug discovery and development

4. Applications of Fluorine in Medicinal Chemistry

5. Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

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