Synthesis and application of well-defined [Ph4P]+[Cu(CF2CF3)2]− complex as a versatile pentafluoroethylating reagent-Reference-Cited by-同舟云学术

Synthesis and application of well-defined [Ph₄P]⁺[Cu(CF₂CF₃)₂]⁻ complex as a versatile pentafluoroethylating reagent

Published:2024 Issue:29 Volume:15 Page:11550-11556
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dong Tao¹,Shen Qilong²^ORCID,Tsui Gavin Chit¹³^ORCID

Affiliation:

1. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, China

2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Lu, Shanghai, 200032, China

3. Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A well-defined [Ph4P]+[Cu(CF2CF3)2]− complex acts as a versatile pentafluoroethylating reagent for the construction of C(sp3)–, C(sp2)– and C(sp)–CF2CF3 bonds.

Funder

Research Grants Council, University Grants Committee

Chinese University of Hong Kong

National Key Research and Development Program of China

National Natural Science Foundation of China

Chinese Academy of Sciences

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02075H

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