What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes-Reference-Cited by-同舟云学术

What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes

Published:2003-09-09 Issue:20 Volume:42 Page:6172-6174
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Sarkar Biprajit¹,Kaim Wolfgang¹,Klein Axel¹,Schwederski Brigitte¹,Fiedler Jan¹,Duboc-Toia Carole¹,Lahiri Goutam K.¹

Affiliation:

1. Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70550 Stuttgart, Germany, J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, CZ-18223 Prague, Czech Republic, Grenoble High Magnetic Field Laboratory, MPI-CNRS, 25, avenue des Martyrs, BP 166, F-38042 Grenoble Cedex 9, France, and Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic034105p

Reference21 articles.

1. The coordination chemistry of 1,2,4,5-tetrazines

2. What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers

3. An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5)

4. Synthesis and Properties of [Ru2(acac)4(bptz)]n+ (n = 0, 1) and Crystal Structure of [Ru2(acac)4(bptz)]

5. Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties

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