A dinuclear [{(p-cym)RuIICl}2(μ-bpytz˙−)]+ complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene)-Reference-Cited by-同舟云学术

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A dinuclear [{(p-cym)RuIICl}2(μ-bpytz˙−)]+ complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene)

Published:2016 Issue:31 Volume:45 Page:12532-12538
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tripathy Suman Kumar¹²³⁴,van der Meer Margarethe⁵⁶⁷⁸,Sahoo Anupam¹²³⁴,Laha Paltan¹²³⁴,Dehury Niranjan¹²³⁴,Plebst Sebastian⁹¹⁰¹¹⁸,Sarkar Biprajit⁵⁶⁷⁸,Samanta Kousik¹²³⁴,Patra Srikanta¹²³⁴

Affiliation:

1. School of Basic Sciences

2. Indian Institute of Technology Bhubaneswar

3. Bhubaneswar - 751007

4. India

5. Institut für Chemie und Biochemie

6. Freie Universität Berlin

7. D-14195 Berlin

8. Germany

9. Institut für Anorganische Chemie

10. Universität Stuttgart

11. Stuttgart

Abstract

p-Cymene as an ancillary ligand favours the stabilisation of a tetrazine radical bridged in a dinuclear [{(p-cym)Ru^II}₂(μ-bpytz˙⁻)]⁺ complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01995A

Reference76 articles.

1. Unconventional Mixed-Valent Complexes of Ruthenium and Osmium

2. Reductive Approach to Mixed Valency (n= 1−) in the Pyrazine Ligand-Bridged [(acac)2Ru(μ-L2–)Ru(acac)2]n(L2–= 2,5-Pyrazine-dicarboxylate) through Experiment and Theory

3. The Role of Bridging Ligands in Controlling Electronic and Magnetic Properties in Polynuclear Complexes

4. Mixed valency in ruthenium complexes—Coordinative aspects

5. Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes

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