An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3

An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5)

Published:1993-06 Issue:12 Volume:32 Page:2640-2643
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Poppe Juergen,Moscherosch Michael,Kaim Wolfgang

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic00064a012

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