Light- and Heavy-Atom Tunneling in Rearrangement Reactions of Cyclopropylcarbenes
Author:
Affiliation:
1. Justus-Liebig University, Heinrich-Buff-Ring 58, 35392 Giessen, Germany
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol2013457
Reference52 articles.
1. Three-Membered-Ring-Based Molecular Architectures
2. Calculations Predict Rapid Tunneling by Carbon from the Vibrational Ground State in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures
3. Calculations Predict a Large Inverse H/D Kinetic Isotope Effect on the Rate of Tunneling in the Ring Opening of Cyclopropylcarbinyl Radical
4. Heavy-atom tunneling as the dominant pathway in a solution-phase reaction? Bond shift in antiaromatic annulenes
5. Carbon Tunneling from a Single Quantum State
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