Calculations Predict Rapid Tunneling by Carbon from the Vibrational Ground State in the Ring Opening of Cyclopropylcarbinyl Radical at Cryogenic Temperatures
Author:
Affiliation:
1. Department of Chemistry, University of North Texas, P.O. Box 305070, Denton, Texas 76203-5070
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja801089p
Reference49 articles.
1. The Tunnel Effect in Chemistry
2. bSheridan, R. S.InReviews in Reactive Intermediate Chemistry;Moss, R. A., Platz, M. S., and Jones, M. J., Jr., Eds.John Wiley & Sons:New York, 2007; p415.
3. Wasserstoffverschiebungen, IV. Kinetischer Isotopeneffekt der 1.5-Wasserstoffverschiebung imcis-Pentadien-(1.3)
4. Vibrationally assisted tunnelling (VAT) in a 1,5 hydrogen shift?
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