Calculations Predict a Large Inverse H/D Kinetic Isotope Effect on the Rate of Tunneling in the Ring Opening of Cyclopropylcarbinyl Radical-Reference-Cited by-同舟云学术

Calculations Predict a Large Inverse H/D Kinetic Isotope Effect on the Rate of Tunneling in the Ring Opening of Cyclopropylcarbinyl Radical

Published:2009-10-15 Issue:44 Volume:131 Page:16002-16003
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Zhang Xue¹,Datta Ayan¹,Hrovat David A.¹,Borden Weston Thatcher¹

Affiliation:

1. Department of Chemistry and Center for Advanced Scientific Computing and Modeling, University of North Texas, 1155 Union Circle #305070, Denton, Texas 76203-5017

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja907406q

Reference23 articles.

1. Reviews:

2. The Tunnel Effect in Chemistry

3. dSheridan, R. S.InReviews in Reactive Intermediate Chemistry;Moss, R. A., Platz, M. S., and Jones, M. J., Jr., Eds.John Wiley & Sons:New York, 2007; pp415−64.

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