An Unusual Dinuclear Ruthenium(III) Complex with a Conjugated Bridging Ligand Derived from Cleavage of a 1,4-Dihydro-1,2,4,5-Tetrazine Ring. Synthesis, Structure, and UV−Vis−NIR Spectroelectrochemical Characterization of a Five-Membered Redox Chain Incorporating Two Mixed-Valence States-Reference-Cited by-同舟云学术

An Unusual Dinuclear Ruthenium(III) Complex with a Conjugated Bridging Ligand Derived from Cleavage of a 1,4-Dihydro-1,2,4,5-Tetrazine Ring. Synthesis, Structure, and UV−Vis−NIR Spectroelectrochemical Characterization of a Five-Membered Redox Chain Incorporating Two Mixed-Valence States

Published:2003-06-24 Issue:15 Volume:42 Page:4707-4713
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Patra Srikanta¹,Miller Thomas A.¹,Sarkar Biprajit¹,Niemeyer Mark¹,Ward Michael D.¹,Lahiri Goutam Kumar¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai-400076, India, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, U.K., and Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic034131n

Reference66 articles.

1. First Example of μ3-Sulfido Bridged Mixed-Valent Triruthenium Complex Triangle RuIII2RuII(O,O-acetylacetonate)3(μ-O,O,γ-C-acetylacetonate)3(μ3-S) (1) Incorporating Simultaneous O,O- and γ-C-Bonded Bridging Acetylacetonate Units. Synthesis, Crystal Structure, and Spectral and Redox Properties

2. Example of Highly Stereoregulated Ruthenium Amidine Complex Formation: Synthesis, Crystal Structures, and Spectral and Redox Properties of the Complexes [RuII(trpy){NC5H4CHNN(C6H5)C(CH3)NH}](ClO4)2 (1) and [RuII(trpy)(NC5H4CHNNHC6H5)Cl]ClO4 (2) (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine)

3. A dinuclear bis(bipyridine)ruthenium(ii) complex, [(bpy)2RuII{L2–}RuII(bpy)2]2+, incorporating an unusual non-innocent bridging ligand containing a p-benzoquinonediimine fragment: synthesis, structure, redox, and UV/VIS/NIR and EPR spectroelectrochemical properties

4. Ruthenium monoterpyridine complexes incorporating α,α′-diimine based ancillary functions. Synthesis, crystal structure, spectroelectrochemical properties and catalytic aspect

5. Mononuclear and dinuclear ruthenium(II)/(III) salicylates incorporating azoimine functionalities as ancillary ligands. Synthesis, spectroscopic and electron-transfer properties†

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