First Example of μ3-Sulfido Bridged Mixed-Valent Triruthenium Complex Triangle RuIII2RuII(O,O-acetylacetonate)3(μ-O,O,γ-C-acetylacetonate)3(μ3-S) (1) Incorporating Simultaneous O,O- and γ-C-Bonded Bridging Acetylacetonate Units. Synthesis, Crystal Structure, and Spectral and Redox Properties
Author:
Affiliation:
1. Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai-400076, India, and Institut fur Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic026221i
Reference58 articles.
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2. Rhodium Acetylacetonate and Iron Tricarbonyl Complexes of Tetracyclone and 3-Ferrocenyl-2,4,5-triphenylcyclopentadienone: An X-ray Crystallographic and NMR Study
3. Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 21. Neutral and cationic β-diketonato-, η3-allylic, and NN″-triazenido-complexes: the X-ray crystal structure of the binuclear complex [Rh2(C5Me5)2(acac)2][BF4]2
4. Cp*Ru(acac)—A Coordinatively Unsaturated, Stable 16-Valence-Electron Complex
5. [Cp*Ru(acac)] Is Not a Coordinatively Unsaturated, Stable 16-Valence-Electron Complex
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