Diruthenium and triruthenium compounds of the potential redox active non-chelated η<sup>1</sup>-N,η<sup>1</sup>-N-benzothiadiazole bridge-Reference-Cited by-同舟云学术

Diruthenium and triruthenium compounds of the potential redox active non-chelated η¹-N,η¹-N-benzothiadiazole bridge

Published:2022 Issue:22 Volume:51 Page:8657-8670
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dey Sanchaita¹,Hazari Arijit Singha¹,Mobin Shaikh M.²^ORCID,Lahiri Goutam Kumar¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India

2. Discipline of Chemistry, Indian Institute of Technology Indore, Simrol, Khandwa Road, Indore-453552, India

Abstract

The redox non-innocent behaviour of non-chelated μ-bis-η1-N,η1-N BTD (2,1,3-benzothiadiazole)-bridged mixed valent diruthenium and triruthenium complexes is attributed to a moderately coupled delocalised electronic state with Vab ≈ 2640–2890 cm−1.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00533F

Reference89 articles.

1. Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts

2. Chemistry of s-, p- and f-block metal complexes with ene-diamido ligands