Example of Highly Stereoregulated Ruthenium Amidine Complex Formation: Synthesis, Crystal Structures, and Spectral and Redox Properties of the Complexes [RuII(trpy){NC5H4CHNN(C6H5)C(CH3)NH}](ClO4)2 (1) and [RuII(trpy)(NC5H4CHNNHC6H5)Cl]ClO4 (2) (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine)-Reference-Cited by-同舟云学术

Example of Highly Stereoregulated Ruthenium Amidine Complex Formation: Synthesis, Crystal Structures, and Spectral and Redox Properties of the Complexes [RuII(trpy){NC5H4CHNN(C6H5)C(CH3)NH}](ClO4)2 (1) and [RuII(trpy)(NC5H4CHNNHC6H5)Cl]ClO4 (2) (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine)

Published:2002-10-04 Issue:22 Volume:41 Page:5831-5836
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Mondal Biplab¹,Puranik Vedavati G.¹,Lahiri Goutam Kumar¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, Bombay, Powai, Mumbai-400076, India, and Physical Chemistry Division, National Chemical Laboratory, Pune, Maharashtra-411008, India

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic020351%2B

Reference62 articles.

1. Ruthenium terpyridine complexes incorporating azo-imine based ancillary ligands. Synthesis, crystal structure, spectroelectrochemical properties and solution reactivities †

2. Ruthenium mononitro and mononitroso terpyridine complexes incorporating azoimine based ancillary ligands. Synthesis, crystal structure, spectroelectrochemical properties and kinetic aspects †

3. Ruthenium-(II)/-(III) terpyridine complexes incorporating imine functionalities. Synthesis, structure, spectroscopic and electrochemical properties †

4. Chemistry of [Ru(tpy)(pap)(L′)n+ (tpy = 2,2′,6′,2″-terpyridine; pap = 2-(phenylazo)pyridine; L′ = Cl−, H2O, CH3CN, 4-picoline, N3−; n = 1,2). X-ray crystal structure of [Ru(tpy)(pap)(CH3CN)](ClO4)2 and catalytic oxidation of water to dioxygen by [Ru(tpy)(pap)(H2O)]2+

5. Redox Properties and Electrocatalytic Activity of the Oxo/Aqua System [Ru(terpy)(bpz)(O)]2+/[Ru(terpy)(bpz)(H2O)]2+. X-ray Crystal Structure of [Ru(terpy)(bpz)Cl]PF6.cntdot.MeCN (terpy = 2,2',2''-Terpyridine; bpz = 2,2'-Bipyrazine)

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