The First Example of Isomerization of a Dimetal Complex Involving the Switch of a Metal−Metal Bond Order from 3 to 0. Synthesis and Characterization of the Paramagnetic Mixed-Valence Complex Cation [(XylNC)(OC)Re(μ-Cl)2(μ-dppm)2ReCl(CNXyl)]+ 1-Reference-Cited by-同舟云学术

The First Example of Isomerization of a Dimetal Complex Involving the Switch of a Metal−Metal Bond Order from 3 to 0. Synthesis and Characterization of the Paramagnetic Mixed-Valence Complex Cation [(XylNC)(OC)Re(μ-Cl)2(μ-dppm)2ReCl(CNXyl)]+ 1

Published:1996-01-01 Issue:51 Volume:118 Page:13091-13092
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Wu Wengan¹,Fanwick Phillip E.¹,Walton Richard A.¹

Affiliation:

1. Department of Chemistry, Purdue University 1393 Brown Building, West Lafayette, Indiana 47907-1393

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja962910f

Reference17 articles.

1. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with isocyanides. 4. Isomerism in mixed carbonyl-isocyanide complexes of stoichiometry [Re2Cl3(dppm)2(CO)2(CNR)]n+ (n = 0 or 1) and [Re2Cl3(dppm)2(CO)(CNR)2]+ (R = tert-Bu or xylyl), which possess edge-shared bioctahedral structures

2. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides VI. Further studies on isomers of the edge-sharing bioctahedral species [Re2C13(μ-dppm)2(CO)(CNxyl)2]+

3. Monocarbonyl Complexes of the Type Re2X4(.mu.-dppm)2(CO) (X = Cl, Br; dppm = Ph2PCH2PPh2) Revisited. Reactions of the Bromo Complex Re2Br4(.mu.-dppm)2(CO) with tert-Butyl and Xylyl Isocyanides

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Reactions of the Dirhenium(II) Complex Re2Cl4(μ-dppm)2 with Pyridinecarboxylic Acids. Examples of Bidentate O,O versus N,O Coordination and Tridentate O,N,O Coordination and Structural Isomers That Contain the Pyridine-2,6-dicarboxylate Ligand;Inorganic Chemistry;2003-08-22

2. Complexation of the Triply-Bonded Dirhenium(II) Complex Re2Cl4(μ-dppm)2 (dppm = Ph2PCH2PPh2) by Up to Three Acetylene Molecules;Inorganic Chemistry;2003-01-24

3. An unusual compound containing μ-O-bridged Re26+ cores in very different coordination environments;Inorganica Chimica Acta;2002-05

4. Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 21.1 A Comparison with the Complexes Re2Cl4(μ-dppE)2 and Re2Cl4(μ-dcpm)2 (dppE = Ph2PC(CH2)PPh2; dcpm = Cy2PCH2PCy2) and the Structural Characterization of Complexes of the Types Re2Cl4(μ-LL)2(CNR), Re2Cl4(μ-LL)2(CNR)2, and [Re2Cl3(μ-LL)2(CNR)3]+ (LL = dppm, dppE, dcpm; R = t-Bu, Xyl);Inorganic Chemistry;2000-05-19

5. Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 19.1 Studies of the Reactions of Five Structural Isomers of Re2Cl2(μ-dppm)2(CO)(CNXyl)3 That Lead to the Dirhenium(I) Complexes [Re2(μ-Cl)(μ-CO)(μ-dppm)2(CNXyl)4]O3SCF3 and [Re2Cl(μ-dppm)2(CO)(CNXyl)3(NCCH3)]O3SCF3;Inorganic Chemistry;1999-10-15