Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 21.1 A Comparison with the Complexes Re2Cl4(μ-dppE)2 and Re2Cl4(μ-dcpm)2 (dppE = Ph2PC(CH2)PPh2; dcpm = Cy2PCH2PCy2) and the Structural Characterization of Complexes of the Types Re2Cl4(μ-LL)2(CNR), Re2Cl4(μ-LL)2(CNR)2, and [Re2Cl3(μ-LL)2(CNR)3]+ (LL = dppm, dppE, dcpm; R = t-Bu, Xyl)
Author:
Affiliation:
1. Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic000064a
Reference36 articles.
1. Reactions of the dirhenium(II) complexes Re2X4(μ-dppm)2 (X=Cl, Br; dppm =Ph2PCH2PPh2) with isocyanides
2. Reactions of Re2Cl4(dppm)2 with carbon monoxide that proceed with retention of the metal-metal bond: synthesis of Re2Cl4(dppm)2(CO)n (n = 1, 2) and the structural characterization of Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)
3. Mixed carbonyl-isocyanide and carbonyl-nitrile complexes derived from the reactions of the multiply bonded dirhenium(II) complexes Re2X4(dppm)2(CO) (X = chloro or bromo-; dppm = Ph2PCH2PPh2). The structural characterization of Cl2Re(.mu.-Cl)(.mu.-dppm)2ReCl(CO) and Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CNxylyl)
4. Carbonylation of the triply bonded dirhenium(II) complexes Re2X4(dppm)2 (X = chloro, bromo; dppm = bis(diphenylphosphino)methane) to give [Re2X3(dppm)2(CO)3]PF6 and [Re2X3(dppm)2(CO)2]PF6. Structural characterization of [(CO)ClRe(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)]PF6
5. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X= Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides. Part IX. New isomeric forms of the mixed carbonyl-isocyanide dirhenium(II) Complexes Re2 Cl4(dppm)2(CO)(CNxyl) and [Re2Cl3(dppm)2(CO)(CNxyl)2]O3SCF3 The X-ray crystal structure of [(xyl NC)2ClRe(?-dppm)2ReCl2(CO)] O3SCF3
Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Dirhenium and dimolybdenum complexes of di(isopropylphosphino)methane;Inorganica Chimica Acta;2001-10
2. Reaction of Re2(μ-O2CCH3)4Cl2 with Bis(dicyclohexylphosphino)methane (dcpm): Isolation of the Mixed-Valent Complex O3ReReCl(η2-dcpm)2 Containing an Unsupported Re−Re Bond;Inorganic Chemistry;2001-05-02
3. The structural characterization of Re2Cl4(μ-dcpm)2 (dcpm=Cy2PCH2PCy2) and a new crystallographic form of Re2Cl4(μ-dppm)2 (dppm=Ph2PCH2PPh2);Inorganica Chimica Acta;2000-12
4. Reactions of the dirhenium(II) complexes Re2X4(mu-dppm)(2) (X = Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides. XXII. A comparison of mixed carbonyl-isocyanide complexes with those formed by Re2Cl4(mu-dcpm)(2) (dcpm = Cy2PCH2PCy2);Journal of Cluster Science;2000
5. Rhenium Compounds;Multiple Bonds Between Metal Atoms
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