Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 19.1 Studies of the Reactions of Five Structural Isomers of Re2Cl2(μ-dppm)2(CO)(CNXyl)3 That Lead to the Dirhenium(I) Complexes [Re2(μ-Cl)(μ-CO)(μ-dppm)2(CNXyl)4]O3SCF3 and [Re2Cl(μ-dppm)2(CO)(CNXyl)3(NCCH3)]O3SCF3
Author:
Affiliation:
1. Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic990538%2B
Reference21 articles.
1. Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 18.1 The Isolation and Characterization of Isomers of the [Re2Cl2(μ-dppm)2(CO)(CNXyl)3]2+ Cation and Its Monocationic and Neutral Congeners
2. Reactions of Re2Cl4(dppm)2 with carbon monoxide that proceed with retention of the metal-metal bond: synthesis of Re2Cl4(dppm)2(CO)n (n = 1, 2) and the structural characterization of Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)
3. Mixed carbonyl-isocyanide and carbonyl-nitrile complexes derived from the reactions of the multiply bonded dirhenium(II) complexes Re2X4(dppm)2(CO) (X = chloro or bromo-; dppm = Ph2PCH2PPh2). The structural characterization of Cl2Re(.mu.-Cl)(.mu.-dppm)2ReCl(CO) and Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CNxylyl)
4. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X= Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides. Part IX. New isomeric forms of the mixed carbonyl-isocyanide dirhenium(II) Complexes Re2 Cl4(dppm)2(CO)(CNxyl) and [Re2Cl3(dppm)2(CO)(CNxyl)2]O3SCF3 The X-ray crystal structure of [(xyl NC)2ClRe(?-dppm)2ReCl2(CO)] O3SCF3
5. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with isocyanides. 4. Isomerism in mixed carbonyl-isocyanide complexes of stoichiometry [Re2Cl3(dppm)2(CO)2(CNR)]n+ (n = 0 or 1) and [Re2Cl3(dppm)2(CO)(CNR)2]+ (R = tert-Bu or xylyl), which possess edge-shared bioctahedral structures
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3. An unexpected product isolated during the decomposition of an isomer of Re2Cl2(μ-dppm)2(CO)(CNXyl)3—synthesis and structural characterization of [Na(dppmO2)3]Cl·2H2O·C6H6;Inorganica Chimica Acta;2000-11
4. Mixed carbonyl–nitrile complexes of dirhenium(II). The structural characterization and reactivity of salts of the [Re2Cl3(μ-dppm)2(CO)(NCMe)n]+ cations (dppm=Ph2PCH2PPh2, n=1 or 2);Journal of Organometallic Chemistry;2000-06
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