Bromine as the Ortho-Directing Group in the Aromatic Metalation/Silylation of Substituted Bromobenzenes
Author:
Affiliation:
1. Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo034790h
Reference21 articles.
1. Directed ortho metalation. Tertiary amide and O-carbamate directors in synthetic strategies for polysubstituted aromatics
2. Directed lithiation of aromatic tertiary amides: an evolving synthetic methodology for polysubstituted aromatics
3. Fluorine as an ortho-directing group in aromatic metalation: Generality of the reaction and the high position of fluorine in the Dir-Met potency scale
4. Regiospecific synthesis of mixed 2,3-dihalobenzoic acids and related acetophenones via ortho-metalation reactions
5. Regioselective ortho-lithiation of chloro and bromo substituted fluoroarenes
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