Palladium-catalyzed C–Si bond formation <i>via</i> denitrative cross-coupling of nitroarenes with hexamethyldisilane-Reference-Cited by-同舟云学术

Palladium-catalyzed C–Si bond formation via denitrative cross-coupling of nitroarenes with hexamethyldisilane

Published:2023 Issue:2 Volume:10 Page:524-530
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yao Jiaxin¹,Yu Lin¹^ORCID,Duan Wengui¹,Li Chao-Jun²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Guangxi University, Guangxi Key Laboratory of Electrochemical Energy Materials, No. 100, East Daxue Road, Nanning, Guangxi 530004, P. R. China

2. Department of Chemistry and FRQNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada

Abstract

We disclose a novel protocol for arylsilane via a Pd-catalyzed cross-coupling of hexamethyldisilane with nitroarenes, and the products could be easily transformed into aryl halides, homocoupling products, and aryl boron reagents.

Funder

Guangxi University

Natural Science Foundation of Guangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01764D

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