Affiliation:
1. Department of Analytical Chemistry and Applied Spectroscopy, Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland
2. Bunge Polska Sp. z o.o., Niepodległości 42, 88-150 Kruszwica, Poland
Abstract
The consumption of cold-pressed oils (CPOs) has continuously increased due to their health-promoting compounds, such as polyunsaturated fatty acid (PUFA), tocopherols, sterols, and polyphenols. This study focused on the estimation and comparison of the physicochemical properties and sensory quality of six CPOs: linseed oil (CPLO), pumpkin oil (CPPO), milk thistle oil (CPMTO), rapeseed oil (CPRO), camelina oil (CPCO), and sunflower oil (CPSO), which are the most popular in the Polish market. These oils were analysed for their fatty acid composition (FAC), their tocopherol, sterol, polycyclic aromatic hydrocarbon (PAHs), water, and volatile matter (WVM) contents, as well as their antioxidant activity (AA) and oxidative stability parameters. Moreover, quantitative descriptive analysis (QDA) was performed to obtain detailed information on the sensory profiles and quantitative data on the CPOs’ attributes that affected consumer acceptability and purchase intent. All of the analysed CPOs were rich in PUFA (27.94–68.42%). They were characterised by the different total amounts of health-beneficial compounds, such as tocopherols (TTC = 44.04–76.98 mg/100 g), sterols (TSC = 300–684 mg/100 g), and polyphenols (TPC = 2.93–8.32 mg GA/100 g). Additionally, their AA was determined using 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), and ferric reducing antioxidant power (FRAP) methods, with results ranging between 185.36–396.63, 958.59–1638.58, and 61.93–119.21 µmol TE/100 g, respectively. However, the deterioration parameters of CPOs, such as peroxide values (PV = 0.24–4.61 meq O2/kg), p-anisidine values (pAnV = 0.39–4.77), acid values (AV = 0.31–2.82 mg KOH/g), and impurity amounts (Σ4PAHs = 1.16–8.76 μg/kg and WVM = 0.020–0.090%), did not exceed the level recommended by the Codex Alimentarius Commission. The obtained results indicated that all of the investigated CPOs are valuable sources of health-promoting bioactive compounds.
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Reference70 articles.
1. Codex Alimentarius (2023, April 25). Codex Standard for Named Vegetable Oils. Codex-Stan 210-1999. Available online: https://tinyurl.com/46s68uzu.
2. Quality Evaluation of Cold Pressed Sunflower Oils by Sensory and Chemical Analysis;Bendini;Eur. J. Lipid Sci. Technol.,2011
3. Revealing the Relationship between Vegetable Oil Composition and Oxidative Stability: A Multifactorial Approach;Castellano;J. Food Compos. Anal.,2018
4. Grajzer, M., Szmalcel, K., Kuźmiński, Ł., Witkowski, M., Kulma, A., and Prescha, A. (2020). Characteristics and Antioxidant Potential of Cold-Pressed Oils—Possible Strategies to Improve Oil Stability. Foods, 9.
5. The Antioxidant Activity and Oxidative Stability of Cold-Pressed Oils;Prescha;J. Am. Oil Chem. Soc.,2014