Microwave-Prepared Quantum Dots and Their Potential Applications as Adsorbents and Chemosensors

Abstract

A combination of different eco-friendly materials prepared promising fluorescent quantum dots (QDs) through the one-step process using the microwave heating of urea with cellulose, chitosan, and biochar. Characterizations of the prepared QDs, including the investigation of their structure by infrared spectroscopy, Raman analysis, X-ray diffraction, thermal gravimetric analysis, morphology, and optical properties, were performed. The results showed that QDs possess a small size, high UV absorption, and excitation wavelength-dependent fluorescence. The prepared QDs were also tested for metal ions removal from aqueous solutions. The adsorption at different contact times was investigated to optimize the adsorption efficiency of the prepared QDs. All QDs were found to be an ideal sorbent for Cr(II), Cu(II), Mn(II), and Pb(II). From the data, Cr(II) was more highly adsorbed than other metal ions. The results of the kinetic investigation showed that the pseudo-second-order kinetic model fit the adsorption process effectively. In addition, the fluorescence spectra of QDs were changed after the adsorption of metal ions; hence, the prepared QDs could be utilized in environmental sectors such as wastewater pollution detection, adsorption, and chemical sensing applications.