Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent

Abstract

AbstractFluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R2, the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB.