HCl Gas Sensor Coating Based on Poly(N-isopropylacrylamide) Nanoparticles Prepared from Water-Methanol Binary Solvent

Abstract

Poly(N-isopropylacrylamide) (PNIPAM) nanoparticles formed in water-methanol binary solvent were successfully deposited on a resonator surface at room temperature by exploiting the cononsolvency effect on the phase transition of PNIPAM aqueous solutions. Scanning electron microscopic observation revealed that the nanoparticles were secondary and made up of agglomerated primary spherical particles of about 10-nm diameter, buried in the film. The magnitude of the sensor response toward HCl gas was larger than that of the nanoparticle sensor prepared from pure water solvent, and the sensitivity to 1 ppm of HCl of sensor-coated nanoparticles based on the present method was 3.3 Hz/ppm. The recovery of the sensors was less than 90% at first cycle measurement, but had improved to almost 100% at the third cycle.